Atmospheric deposition of organochlorine contaminants to Galveston Bay, Texas

Atmospheric monitoring of PCBs and chlorinated pesticides (e.g., HCHs, chlordanes, and DDTs) in Galveston Bay was conducted at Seabrook, Texas. Air and wet deposition samples were collected from 2 February 1995 and continued through 6 August 1996. Vapor total PCB (tPCB) concentrations in air ranged from 0.21 to 4.78 ng m(-3) with a dominance of tri-chlorinated PCBs. Dissolved tPCBs in rain ranged From 0.08 to 3.34 ng l(-1), with tetra-chlorinated PCBs predominating. The predominant isomers found in air and rain were alpha- and gamma -HCH, alpha- and gamma -chlordanes, 4,4 ' -DDT, and dieldrin, The concentrations of PCBs and pesticides in the air and rain revealed no clear seasonal trend. Elevated levels of PCBs in the air occurred when temperatures were high and wind came from urban and industrialized areas (S, SW, NW, and W of the site). Concentrations of HCHs were elevated in April. May, and October, perhaps due to local and:or regional applications of gamma -HCH (lindane). Other pesticides showed no notable temporal variation. When winds originated From the G ulf of Mexico (southeasterly), lower concentrations of organochlorines were detected in the air. The direct deposition rate (wet + dry) of PCBs to Galveston Bay (6.40 mug m(-2) yr(-1)) was significantly higher than that of pesticides by a factor of 5-10. The net flux from gas exchange estimated for PCBs was from Galveston Bay water to the atmosphere (78 mug m(-1) yr(-1)). Gas exchange of PCBs from bay water to the atmosphere was the dominant flux. (C) 2001 Elsevier Science Ltd. All rights reserved