Laboratory investigation of chemical and physical properties of soot-containing aerosols

Show simple item record


dc.contributor.advisor Zhang , Renyi en_US
dc.contributor.committeeMember Collins , Don en_US
dc.creator Zhang , Dan en_US
dc.date.accessioned 2006 -08 -16T19 :12 :00Z
dc.date.accessioned 2014 -02 -19T19 :25 :56Z
dc.date.available 2006 -08 -16T19 :12 :00Z
dc.date.available 2014 -02 -19T19 :25 :56Z
dc.date.created 2003 -05 en_US
dc.date.issued 2006 -08 -16T19 :12 :00Z
dc.identifier.uri http : / /hdl .handle .net /1969 .1 /3977
dc.description.abstract Soot particles released from fossil fuel combustion and biomass burning have a large impact on the regional /global climate by altering the atmospheric radiative properties and by serving as cloud condensation nuclei (CCN ) . However , the exact forcing is affected by the mixing of soot with other aerosol constituents , such as sulfuric acid . In this work , experimental studies have been carried out focusing on three integral parts : (1 ) heterogeneous uptake of sulfuric acid on soot ; (2 ) hygroscopic growth of H2SO4 -coated soot aerosols ; (3 ) effect of H2SO4 coating on scattering and extinction properties of soot particles . A low -pressure laminar -flow reactor , coupled to ion driftchemical ionization mass spectrometry (ID -CIMS ) detection , is used to study uptake coefficients of H2SO4 on combustion soot . The results suggest that uptake of H2SO4 takes place efficiently on soot particles , representing an important route to convert hydrophobic soot to hydrophilic aerosols . A tandem differential mobility analyzing (TDMA ) system is employed to determine the hygroscopicity of freshly generated soot in the presence of H2SO4 coating . It is found that fresh soot particles are highly hydrophobic , while coating of H2SO4 significantly facilitates water uptake on soot even at sub -saturation relative humidities . The results indicate that aged soot particles in the atmosphere can potentially be an efficient source of CCN . Scattering and extinction coefficient measurements of the soot -H2SO4 mixed particles are conducted using a threewavelength Nephelometer and a multi -path extinction cell . Coating of H2SO4 is found to increase the single scattering albedo (SSA ) of soot particles which has impact on the aerosol direct radiative effect . Other laboratory techniques such as transmission electron microscopy (TEM ) and Fourier transform infrared spectrometry (FTIR ) are utilized to examine the morphology and chemical composition of the soot -H2SO4 particles . This work provides critical information concerning the heterogeneous interaction of soot and sulfuric acid , and how their mixing affects the hygroscopic and optical properties of soot . The results will improve our ability to model and assess the soot direct and indirect forcing and hence enhance our understanding of the impact of anthropogenic activities on the climate . en_US
dc.format.extent 11678399 bytes
dc.format.medium electronic en_US
dc.format.mimetype application /pdf
dc.language.iso en _US en_US
dc.publisher Texas A &M University en_US
dc.subject soot en_US
dc.title Laboratory investigation of chemical and physical properties of soot -containing aerosols en_US
dc.type Book en
dc.type.genre Electronic Dissertation en_US
dc.type.material text en_US
dc.format.digitalOrigin born digital en_US

Citation

Laboratory investigation of chemical and physical properties of soot-containing aerosols. Available electronically from http : / /hdl .handle .net /1969 .1 /3977 .

Files in this item

Files Size Format View

There are no files associated with this item.

This item appears in the following Collection(s)

Show simple item record

Search DSpace

Advanced Search

Browse